Recent advances in metal–organic framework-derived materials for electrocatalytic and photocatalytic CO2 reduction

Zheng，Yu Tao; Li，Shumin; Huang，Ning Yu; Li，Xinran; Xu，Qiang

2024-07-01

10.1016/j.ccr.2024.215858

Coordination Chemistry Reviews   影响因子和分区

0010-8545

The extensive combustion of fossil fuels along with uncontrolled release of carbon dioxide (CO) has led to severe environmental contamination and global greenhouse effects. Carbon neutrality and low-carbon development are urgent demands for the enduring progress of human society. The utilization of electrocatalytic and photocatalytic reduction reaction to convert CO into valuable chemicals is viewed as a hopeful approach for addressing environmental issues and energy crises. Metal-organic frameworks (MOFs) are discovered to have extensive applications in the areas of electrocatalysis and photocatalysis because of their high porosity, versatile compositions and structural tunability. With the help of designed MOF structures and specific synthesis methods, it is convenient and targeted to regulate the morphologies and electronic structures of MOF-derived materials with higher stability, further affecting their catalytic performance towards CO reduction. In order to enhance catalytic performance to meet application requirements, it is essential to investigate the relationship between the morphologies, electronic structures of MOF-derived materials and their performances. In this review, to reveal the reaction mechanisms and provide theoretical support for catalyst design, the fundamentals of CO reduction through electrocatalytic and photocatalytic pathways are discussed. Subsequently, an overview of the developments in MOF-derived materials for electrocatalytic and photocatalytic CO reduction is presented, focusing on different optimization strategies such as morphology control and electronic modification. Finally, we outline the difficulties and opportunities for advancing MOF-derived materials in electrocatalytic and photocatalytic CO reduction, along with the strategies for developing electrocatalysts and photocatalysts with excellent performance.

CO2 reduction Electrocatalysis Electronic structure MOF-derived materials Morphology Photocatalysis

英语

第一

CHEMISTRY

2-s2.0-85190236112

Scopus

Shenzhen Key Laboratory of Micro/Nano-Porous Functional Materials (SKLPM),Department of Chemistry,Department of Materials Science and Engineering and SUSTech Academy for Advanced Interdisciplinary Studies,Southern University of Science and Technology (SUSTech),Shenzhen,518055,China

Zheng，Yu Tao,Li，Shumin,Huang，Ning Yu,等. Recent advances in metal–organic framework-derived materials for electrocatalytic and photocatalytic CO2 reduction[J]. Coordination Chemistry Reviews,2024,510.

Zheng，Yu Tao,Li，Shumin,Huang，Ning Yu,Li，Xinran,&Xu，Qiang.(2024).Recent advances in metal–organic framework-derived materials for electrocatalytic and photocatalytic CO2 reduction.Coordination Chemistry Reviews,510.

Zheng，Yu Tao,et al."Recent advances in metal–organic framework-derived materials for electrocatalytic and photocatalytic CO2 reduction".Coordination Chemistry Reviews 510(2024).