| 题名 | Organocatalytic Regio- and Enantioselective Allylic Alkylation of Indolin-2-imines with MBH Carbonates toward 3-Allylindoles |
| 作者 | |
| 通讯作者 | Li, Pengfei |
| 发表日期 | 2023
|
| DOI | |
| 发表期刊 | |
| ISSN | 0022-3263
|
| EISSN | 1520-6904
|
| 卷号 | 88期号:12页码:7810-7814 |
| 摘要 | An organocatalytic asymmetric C3-allylic alkylation of indolone-2-imines with MBH carbonates has been developed for the first time. As opposed to previous reports, an "interrupted" annulation was achieved, affording 3-allylindoles in generally high yields with excellent stereoselectivities. The representative scale-up reaction and transformation of 3-allylindoles were examined. A possible mechanism was also proposed. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 通讯
|
| 资助项目 | National Natural Science Foundation of China[21871128]
; Guangdong Innovative Program[2019BT02Y335]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Organic
|
| WOS记录号 | WOS:000925702800001
|
| 出版者 | |
| EI入藏号 | 20230513536088
|
| EI主题词 | Alkylation
; Allylation
|
| EI分类号 | Chemical Reactions:802.2
; Inorganic Compounds:804.2
|
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]:4
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://kc.sustech.edu.cn/handle/2SGJ60CL/479593 |
| 专题 | 深圳格拉布斯研究院 理学院_化学系 |
| 作者单位 | 1.Harbin Inst Technol, Sch Resources & Environm, Harbin 150080, Peoples R China 2.Southern Univ Sci & Technol SUSTech, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol SUSTech, Coll Sci, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China |
| 通讯作者单位 | 深圳格拉布斯研究院; 化学系 |
| 推荐引用方式 GB/T 7714 |
Chen, Lunfeng,Li, Pengfei. Organocatalytic Regio- and Enantioselective Allylic Alkylation of Indolin-2-imines with MBH Carbonates toward 3-Allylindoles[J]. JOURNAL OF ORGANIC CHEMISTRY,2023,88(12):7810-7814.
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| APA |
Chen, Lunfeng,&Li, Pengfei.(2023).Organocatalytic Regio- and Enantioselective Allylic Alkylation of Indolin-2-imines with MBH Carbonates toward 3-Allylindoles.JOURNAL OF ORGANIC CHEMISTRY,88(12),7810-7814.
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| MLA |
Chen, Lunfeng,et al."Organocatalytic Regio- and Enantioselective Allylic Alkylation of Indolin-2-imines with MBH Carbonates toward 3-Allylindoles".JOURNAL OF ORGANIC CHEMISTRY 88.12(2023):7810-7814.
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| 条目包含的文件 | 条目无相关文件。 | |||||
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