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题名	Highly efficient synthesis of chiral β-amino phosphine derivatives via direct asymmetric reductive amination with ammonium salts and H2
作者	Liu，Yufeng1 ; Wang，Linzhou 1; Li，Yingjun2,3 ; Ma，Baode1 ; Chen，Gen Qiang1,3 ; Zhang，Xumu1,2
通讯作者	Ma，Baode; Zhang，Xumu
发表日期	2022-06-24
DOI	10.1016/j.gresc.2022.06.005
发表期刊	Green Synthesis and Catalysis 影响因子和分区
EISSN	2666-5549
卷号	3 期号:3
摘要	A highly efficient and enantioselective method for the asymmetric reductive amination of β-keto phosphine derivatives was disclosed, and the corresponding β-amino phosphine oxides could be obtained in high yields (up to 97% yield) and excellent enantioselectivities (up to 97% ee). Moreover, the reaction worked well on a gram scale, indicating that our protocol has potential applications in the synthesis of chiral ligands and organocatalysts.
关键词	Ammonium Salt Asymmetric Reductive Amination Chiral Β-amino Phosphine Ruthenium-catalysed
相关链接	[Scopus记录]
收录类别	SCI ; SSCI ; ESCI
语种	英语
学校署名	第一 ; 通讯
资助项目	National Natural Science Foundation of China[21901107] ; National Natural Science Foundation of China["21901107","2020B010188001","2022B1515020055"] ; Shenzhen Bay Laboratory[22171129] ; Shenzhen Science and Technology Innovation Committee["22001113","2020KCXTD016"] ; Key-Area Research and Development Program of Guangdong Province[SZBL2019062801006] ; Stable Support Plan Program of Shenzhen Science and Technology Innovation Committee[KQTD20150717103157174] ; Innovative Team of Universities in Guangdong Province[JCYJ20210324104202007] ; Guangdong Basic and Applied Basic Research Foundation[20200925161222002]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:001025341600001
出版者	KEAI PUBLISHING LTD
来源库	Web of Science
引用统计	被引频次[WOS]：7
成果类型	期刊论文
条目标识符	http://kc.sustech.edu.cn/handle/2SGJ60CL/359574
专题	理学院_化学系前沿与交叉科学研究院
作者单位	1.Medi-X Pingshan,Guangdong Provincial Key Laboratory of Catalysis,and Department of Chemistry,Southern University of Science and Technology,Shenzhen,518000,China 2.Shenzhen Bay Laboratory,Shenzhen,518132,China 3.Academy for Advanced Interdisciplinary Studies and Southern University of Science and Technology,Shenzhen,518000,China
第一作者单位	化学系
通讯作者单位	化学系
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Liu，Yufeng,Wang，Linzhou,Li，Yingjun,et al. Highly efficient synthesis of chiral β-amino phosphine derivatives via direct asymmetric reductive amination with ammonium salts and H2[J]. Green Synthesis and Catalysis,2022,3(3).
APA	Liu，Yufeng,Wang，Linzhou,Li，Yingjun,Ma，Baode,Chen，Gen Qiang,&Zhang，Xumu.(2022).Highly efficient synthesis of chiral β-amino phosphine derivatives via direct asymmetric reductive amination with ammonium salts and H2.Green Synthesis and Catalysis,3(3).
MLA	Liu，Yufeng,et al."Highly efficient synthesis of chiral β-amino phosphine derivatives via direct asymmetric reductive amination with ammonium salts and H2".Green Synthesis and Catalysis 3.3(2022).