| 题名 | Highly efficient synthesis of chiral aromatic ketones via Rh-catalyzed asymmetric hydrogenation of beta,beta-disubstituted enones |
| 作者 | |
| 通讯作者 | Geng, Huiling; Zhang, Xumu |
| 发表日期 | 2017-08-25
|
| DOI | |
| 发表期刊 | |
| ISSN | 1359-7345
|
| EISSN | 1364-548X
|
| 卷号 | 53期号:66页码:9258-9261 |
| 摘要 | A succinct and efficient protocol was developed for the synthesis of chiral aromatic ketones via asymmetric hydrogenation of beta,beta-disubstituted enones with rhodium catalysts based on chiral bisphosphine thiourea ligands. A series of substrates (17 examples) was smoothly catalyzed to afford the corresponding chiral aromatic ketones in high conversions (>99%) with excellent enantioselectivities (up to 96% ee). |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 重要成果 | NI期刊
; NI论文
|
| 学校署名 | 通讯
|
| 资助项目 | National Natural Science Foundation of China[31301712]
; National Natural Science Foundation of China[31572038]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
|
| WOS记录号 | WOS:000407633900018
|
| 出版者 | |
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：19
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://kc.sustech.edu.cn/handle/2SGJ60CL/28704 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Northwest A&F Univ, Sch Pharm & Chem, Yangling 712100, Shaanxi, Peoples R China 2.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 3.Fourth Mil Med Univ, Sch Chem & Pharm, Xian 710032, Shaanxi, Peoples R China 4.South Univ Sci & Technol, Dept Chem, Guangzhou 518055, Guangdong, Peoples R China |
| 通讯作者单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Zhang, Tao,Jiang, Jun,Yao, Lin,et al. Highly efficient synthesis of chiral aromatic ketones via Rh-catalyzed asymmetric hydrogenation of beta,beta-disubstituted enones[J]. CHEMICAL COMMUNICATIONS,2017,53(66):9258-9261.
|
| APA |
Zhang, Tao,Jiang, Jun,Yao, Lin,Geng, Huiling,&Zhang, Xumu.(2017).Highly efficient synthesis of chiral aromatic ketones via Rh-catalyzed asymmetric hydrogenation of beta,beta-disubstituted enones.CHEMICAL COMMUNICATIONS,53(66),9258-9261.
|
| MLA |
Zhang, Tao,et al."Highly efficient synthesis of chiral aromatic ketones via Rh-catalyzed asymmetric hydrogenation of beta,beta-disubstituted enones".CHEMICAL COMMUNICATIONS 53.66(2017):9258-9261.
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| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| c7cc04045h.pdf（1932KB） | -- | -- | 限制开放 | -- | ||
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