| 题名 | Highly enantioselective transfer hydrogenation of racemic alpha-substituted beta-keto sulfonamides via dynamic kinetic resolution |
| 作者 | |
| 通讯作者 | Lv, Hui; Zhang, Xumu |
| 发表日期 | 2018-04-17
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| DOI | |
| 发表期刊 | |
| ISSN | 1359-7345
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| EISSN | 1364-548X
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| 卷号 | 54期号:31页码:3883-3886 |
| 摘要 | Highly enantioselective transfer hydrogenation of -keto sulfonamides was developed via dynamic kinetic resolution using a chiral Ru(ii) catalyst with an azeotropic solution of HCO2H/Et3N as a hydrogen donor, affording -substituted -hydroxyl sulfonamides in good yields with excellent diastereo- and enantioselectivities. This method is featured with mild conditions, easy operation, and a broad substrate scope, which make it possible to find wide applications in the synthesis of natural products and biologically active compounds containing the -substituted -hydroxyl sulfonamide core. |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
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| 重要成果 | NI期刊
; NI论文
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| 学校署名 | 通讯
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| 资助项目 | CAS Key Laboratory of Molecular Recognition and Function[2017LMRF002]
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| WOS研究方向 | Chemistry
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| WOS类目 | Chemistry, Multidisciplinary
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| WOS记录号 | WOS:000430022100020
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| 出版者 | |
| ESI学科分类 | CHEMISTRY
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| 来源库 | Web of Science
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| 引用统计 |
被引频次[WOS]：20
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://kc.sustech.edu.cn/handle/2SGJ60CL/27812 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 2.Wuhan Univ, Coll Chem & Mol Sci, Minist Educ, Engn Res Ctr Organosilicon Cpds & Mat, Wuhan 430072, Hubei, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China 4.South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China |
| 通讯作者单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Xiong, Zhichao,Pei, Chengfeng,Xue, Peng,et al. Highly enantioselective transfer hydrogenation of racemic alpha-substituted beta-keto sulfonamides via dynamic kinetic resolution[J]. CHEMICAL COMMUNICATIONS,2018,54(31):3883-3886.
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| APA |
Xiong, Zhichao,Pei, Chengfeng,Xue, Peng,Lv, Hui,&Zhang, Xumu.(2018).Highly enantioselective transfer hydrogenation of racemic alpha-substituted beta-keto sulfonamides via dynamic kinetic resolution.CHEMICAL COMMUNICATIONS,54(31),3883-3886.
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| MLA |
Xiong, Zhichao,et al."Highly enantioselective transfer hydrogenation of racemic alpha-substituted beta-keto sulfonamides via dynamic kinetic resolution".CHEMICAL COMMUNICATIONS 54.31(2018):3883-3886.
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| 条目包含的文件 | 条目无相关文件。 | |||||
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