什么软件可以直接买球|买球哪个app好用

题名	Bronsted-Acid-Promoted Rh-Catalyzed Asymmetric Hydrogenation of N-Unprotected Indoles: A Cocatalysis of Transition Metal and Anion Binding
作者	Wen, Jialin1,2 ; Fan, Xiangru 1; Tan, Renchang 3; Chien, Hui-Chun 3; Zhou, Qinghai 1; Chung, Lung Wa1 ; Zhang, Xumu1
通讯作者	Chung, Lung Wa; Zhang, Xumu
发表日期	2018-04-20
DOI	10.1021/acs.orglett.8b00312
发表期刊	ORGANIC LETTERS 影响因子和分区
ISSN	1523-7060
EISSN	1523-7052
卷号	20 期号:8页码:2143-2147
摘要	The incorporation of Bronsted acid, thiourea anion binding, and transition metal catalysis enables an efficient method to synthesize chiral indolines via hydrogenation of indoles. Catalyzed by a rhodium/ZhaoPhos complex, asymmetric hydrogenation of unprotected indoles is performed smoothly with excellent enantioselectivities (up to 99% ee, up to 400 TON). Bronsted acid HCl activates indoles to form iminium ion intermediates. Mechanistic studies support the assumption that anion binding plays a crucial role as a secondary interaction. DFT calculations reveal an outer-sphere mechanism in this chemical transformation.
相关链接	[来源记录]
收录类别	SCI ; IC ; CCR
语种	英语
重要成果	NI期刊 ; NI论文
学校署名	第一 ; 通讯
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000430898200004
出版者	AMER CHEMICAL SOC
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：57
成果类型	期刊论文
条目标识符	http://kc.sustech.edu.cn/handle/2SGJ60CL/27801
专题	理学院_化学系前沿与交叉科学研究院
作者单位	1.Southern Univ Sci & Technol SUSTech, Dept Chem, 1088 Xueyuan Rd, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, 1088 Xueyuan Rd, Shenzhen 518055, Peoples R China 3.Rutgers State Univ, Dept Chem & Chem Biol, 610 Taylor Rd, Piscataway, NJ 08854 USA
第一作者单位	化学系; 前沿与交叉科学研究院
通讯作者单位	化学系
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Wen, Jialin,Fan, Xiangru,Tan, Renchang,et al. Bronsted-Acid-Promoted Rh-Catalyzed Asymmetric Hydrogenation of N-Unprotected Indoles: A Cocatalysis of Transition Metal and Anion Binding[J]. ORGANIC LETTERS,2018,20(8):2143-2147.
APA	Wen, Jialin.,Fan, Xiangru.,Tan, Renchang.,Chien, Hui-Chun.,Zhou, Qinghai.,...&Zhang, Xumu.(2018).Bronsted-Acid-Promoted Rh-Catalyzed Asymmetric Hydrogenation of N-Unprotected Indoles: A Cocatalysis of Transition Metal and Anion Binding.ORGANIC LETTERS,20(8),2143-2147.
MLA	Wen, Jialin,et al."Bronsted-Acid-Promoted Rh-Catalyzed Asymmetric Hydrogenation of N-Unprotected Indoles: A Cocatalysis of Transition Metal and Anion Binding".ORGANIC LETTERS 20.8(2018):2143-2147.