| 题名 | Scope and Mechanism on Iridium-f-Amphamide Catalyzed Asymmetric Hydrogenation of Ketones |
| 作者 | |
| 通讯作者 | Dang, Li; Zhang, Xumu |
| 发表日期 | 2018-09
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| DOI | |
| 发表期刊 | |
| ISSN | 1001-604X
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| EISSN | 1614-7065
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| 卷号 | 36期号:9页码:851-856 |
| 摘要 | A series of novel and easily accessed ferrocene-based amino-phosphine-sulfonamide (f-Amphamide) ligands have been developed and applied in Ir-catalyzed asymmetric hydrogenation of aryl ketones, affording the corresponding chiral secondary alcohols with excellent results (up to >99% conversion, >99% ee and TON up to 200 000). DFT calculations suggest an activating model involving an alkali cation Li+. |
| 关键词 | |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
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| 学校署名 | 第一
; 通讯
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| 资助项目 | National Natural Science Foundation of China[21573102]
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| WOS研究方向 | Chemistry
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| WOS类目 | Chemistry, Multidisciplinary
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| WOS记录号 | WOS:000441435300010
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| 出版者 | |
| ESI学科分类 | CHEMISTRY
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| 来源库 | Web of Science
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| 引用统计 |
被引频次[WOS]：46
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://kc.sustech.edu.cn/handle/2SGJ60CL/27291 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Southern Univ Sci & Technol, Dept Chem, 1088 Xueyuan Rd, Shenzhen 518055, Guangdong, Peoples R China 2.Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China 3.Shantou Univ, Key Lab Preparat & Applicat Ordered Struct Mat Gu, Shantou 515063, Guangdong, Peoples R China |
| 第一作者单位 | 化学系 |
| 通讯作者单位 | 化学系 |
| 第一作者的第一单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Liang, Zhiqin,Yang, Tilong,Gu, Guoxian,et al. Scope and Mechanism on Iridium-f-Amphamide Catalyzed Asymmetric Hydrogenation of Ketones[J]. CHINESE JOURNAL OF CHEMISTRY,2018,36(9):851-856.
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| APA |
Liang, Zhiqin,Yang, Tilong,Gu, Guoxian,Dang, Li,&Zhang, Xumu.(2018).Scope and Mechanism on Iridium-f-Amphamide Catalyzed Asymmetric Hydrogenation of Ketones.CHINESE JOURNAL OF CHEMISTRY,36(9),851-856.
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| MLA |
Liang, Zhiqin,et al."Scope and Mechanism on Iridium-f-Amphamide Catalyzed Asymmetric Hydrogenation of Ketones".CHINESE JOURNAL OF CHEMISTRY 36.9(2018):851-856.
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| 条目包含的文件 | 条目无相关文件。 | |||||
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