| 题名 | Rhodium-Catalyzed Highly Regio- and Enantioselective Hydrogenation of Tetrasubstituted Allenyl Sulfones: An Efficient Access to Chiral Allylic Sulfones |
| 作者 | |
| 通讯作者 | Lv, Hui; Zhang, Xumu |
| 发表日期 | 2018-10
|
| DOI | |
| 发表期刊 | |
| ISSN | 1433-7851
|
| EISSN | 1521-3773
|
| 卷号 | 57期号:40页码:13248-13251 |
| 摘要 | A highly regio- and enantioselective hydrogenation of challenging tetrasubstituted allenyl sulfones has been developed, affording chiral allylic sulfones in good yields with excellent regio- and enantioselectivities (up to 99% yield and 99% ee). This method provides an efficient and concise route to chiral allylic sulfones, thus offering an atom-economic process with a wide range of potential applications in organic synthesis and medicinal chemistry. |
| 关键词 | |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 重要成果 | NI期刊
; NI期刊
; NI论文
|
| 学校署名 | 通讯
|
| 资助项目 | Shenzhen Nobel Prize Scientists Laboratory Project[C17213101]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
|
| WOS记录号 | WOS:000445445700045
|
| 出版者 | |
| EI入藏号 | 20183805836843
|
| EI主题词 | Enantioselectivity
; Hydrogenation
; Rhodium
|
| EI分类号 | Precious Metals:547.1
; Chemistry:801
; Physical Chemistry:801.4
; Chemical Reactions:802.2
|
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：33
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://kc.sustech.edu.cn/handle/2SGJ60CL/27168 |
| 专题 | 理学院_化学系 深圳格拉布斯研究院 |
| 作者单位 | 1.Wuhan Univ, Key Lab Biomed Polymers, Minist Educ, Wuhan 430072, Hubei, Peoples R China 2.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China 4.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China 5.Wuhan Univ, Engn Res Ctr Organosilicon Cpds & Mat, Minist Educ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China |
| 通讯作者单位 | 化学系; 深圳格拉布斯研究院 |
| 推荐引用方式 GB/T 7714 |
Long, Jiao,Shi, Liyang,Li, Xiong,et al. Rhodium-Catalyzed Highly Regio- and Enantioselective Hydrogenation of Tetrasubstituted Allenyl Sulfones: An Efficient Access to Chiral Allylic Sulfones[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(40):13248-13251.
|
| APA |
Long, Jiao,Shi, Liyang,Li, Xiong,Lv, Hui,&Zhang, Xumu.(2018).Rhodium-Catalyzed Highly Regio- and Enantioselective Hydrogenation of Tetrasubstituted Allenyl Sulfones: An Efficient Access to Chiral Allylic Sulfones.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(40),13248-13251.
|
| MLA |
Long, Jiao,et al."Rhodium-Catalyzed Highly Regio- and Enantioselective Hydrogenation of Tetrasubstituted Allenyl Sulfones: An Efficient Access to Chiral Allylic Sulfones".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.40(2018):13248-13251.
|
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
| anie.201804891.pdf（863KB） | -- | -- | 限制开放 | -- | ||
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
; 
修改评论