| 题名 | Kinetics of the simplest criegee intermediate CH2OO reacting with CF3CF=CF2 dagger |
| 作者 | |
| 通讯作者 | Dong, Wen-rui; Yang, Xue-ming |
| 发表日期 | 2020-04
|
| DOI | |
| 发表期刊 | |
| ISSN | 1674-0068
|
| EISSN | 2327-2244
|
| 卷号 | 33期号:2页码:234-238 |
| 摘要 | CF3CF=CF2 is a potential source of atmospheric trifluoroacetic acid (CF3C(O)OH). The kinetics of the reaction of the simplest Criegee intermediate (CH2OO) with CF3CF=CF2 was studied by using the OH laser-induced fluorescence method. At 10 torr, the rate co-efficients were measured to be (1.45 +/- 0.14)x10(-13), (1.18 +/- 0.11)x10(-13), (1.11 +/- 0.08)x10(-13), and (1.04 +/- 0.08)x10(-13) cm(3)center dot molecule(-1)center dot s(-1) at 283, 298, 308 and 318 K, respectively. The activation energy of (-1.66 +/- 0.21) kcal/mol was derived from the Arrhenius equation. No obvious pressure dependence was observed. |
| 关键词 | |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 通讯
|
| 资助项目 | Strategic Priority Research Program of Chinese Academy of Sciences[XDB17000000]
; National Natural Science Foundation of China[21873098]
; International Partnership Program of Chinese Academy of Sciences[121421KYSB20170012]
; Chemical Dynamics Research Center[21688102]
; Liaoning Revitalization Talents Program[XLYC1807248]
|
| WOS研究方向 | Physics
|
| WOS类目 | Physics, Atomic, Molecular & Chemical
|
| WOS记录号 | WOS:000537143100015
|
| 出版者 | |
| EI入藏号 | 20213210738069
|
| EI主题词 | Activation energy
; Reaction intermediates
; Trifluoroacetic acid
|
| EI分类号 | Chemical Reactions:802.2
; Chemical Products Generally:804
; Organic Compounds:804.1
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：1
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://kc.sustech.edu.cn/handle/2SGJ60CL/139981 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Chem Lasers, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 4.Dalian Univ Technol, Sch Environm Sci & Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China 5.Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn, Dalian 116024, Peoples R China 6.Dalian Univ Technol, Sch Phys, Minist Educ, Key Lab Mat Modificat Laser Ion & Electron Beams, Dalian 116024, Peoples R China 7.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China |
| 通讯作者单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Chen, Yang,Zhou, Xiao-hu,Liu, Yi-qiang,et al. Kinetics of the simplest criegee intermediate CH2OO reacting with CF3CF=CF2 dagger[J]. 化学物理学报,2020,33(2):234-238.
|
| APA |
Chen, Yang,Zhou, Xiao-hu,Liu, Yi-qiang,Jin, Yu-qi,Dong, Wen-rui,&Yang, Xue-ming.(2020).Kinetics of the simplest criegee intermediate CH2OO reacting with CF3CF=CF2 dagger.化学物理学报,33(2),234-238.
|
| MLA |
Chen, Yang,et al."Kinetics of the simplest criegee intermediate CH2OO reacting with CF3CF=CF2 dagger".化学物理学报 33.2(2020):234-238.
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| 条目包含的文件 | 条目无相关文件。 | |||||
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