| 题名 | Asymmetric Linear-Selective Hydroformylation of 1,1-Dialkyl Olefins Assisted by a Steric-Auxiliary Strategy |
| 作者 | |
| 通讯作者 | Wen,Jialin; Zhang,Xumu |
| 发表日期 | 2020
|
| DOI | |
| 发表期刊 | |
| ISSN | 1523-7060
|
| EISSN | 1523-7052
|
| 卷号 | 22期号:11页码:4523-4526 |
| 摘要 | Asymmetric hydroformylation of 1,2-dialkyl olefins was reported. In order to increase the enantiomeric induction, steric auxiliary sulfonyl groups were introduced. Using a Rh/Yanphos complex as catalyst, chiral aldehydes were obtained with high enantioselectivities under mild pressure. The easily removable auxiliary made this method a powerful tool in the preparation of important enantiopure building blocks. |
| 相关链接 | [Scopus记录] |
| 收录类别 | |
| 语种 | 英语
|
| 重要成果 | NI期刊
; NI论文
|
| 学校署名 | 第一
; 通讯
|
| 资助项目 | National Natural Science Foundation of China[21672094]
; Shenzhen Nobel Prize Scientists Laboratory Project[C17783101]
; Science, Technology and Innovation Commission of Shenzhen[KQTD20150717103157174][ZDSYS20190902093215877]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Organic
|
| WOS记录号 | WOS:000538848600090
|
| 出版者 | |
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]:8
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://kc.sustech.edu.cn/handle/2SGJ60CL/138269 |
| 专题 | 理学院_化学系 前沿与交叉科学研究院 深圳格拉布斯研究院 |
| 作者单位 | 1.Shenzhen Grubbs Institute,Department of Chemistry,Shenzhen Key Laboratory of Small Molecule Drug Discovery and Synthesis,Southern University of Science and Technology,Shenzhen,1088 Xueyuan Road,518055,China 2.Academy for Advanced Interdisciplinary Studies,Southern University of Science and Technology,Shenzhen,1088 Xueyuan Road,518055,China |
| 第一作者单位 | 化学系; 深圳格拉布斯研究院 |
| 通讯作者单位 | 化学系; 深圳格拉布斯研究院; 前沿与交叉科学研究院 |
| 第一作者的第一单位 | 化学系; 深圳格拉布斯研究院 |
| 推荐引用方式 GB/T 7714 |
Zhang,Dequan,You,Cai,Li,Xiuxiu,et al. Asymmetric Linear-Selective Hydroformylation of 1,1-Dialkyl Olefins Assisted by a Steric-Auxiliary Strategy[J]. ORGANIC LETTERS,2020,22(11):4523-4526.
|
| APA |
Zhang,Dequan,You,Cai,Li,Xiuxiu,Wen,Jialin,&Zhang,Xumu.(2020).Asymmetric Linear-Selective Hydroformylation of 1,1-Dialkyl Olefins Assisted by a Steric-Auxiliary Strategy.ORGANIC LETTERS,22(11),4523-4526.
|
| MLA |
Zhang,Dequan,et al."Asymmetric Linear-Selective Hydroformylation of 1,1-Dialkyl Olefins Assisted by a Steric-Auxiliary Strategy".ORGANIC LETTERS 22.11(2020):4523-4526.
|
| 条目包含的文件 | 条目无相关文件。 | |||||
|
|
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论